As a primer course, check out Bruce Miller's free online audio course. It's still under construction, but has a LOT of useful information. His take on Electric Guitar amping could really help you out:
BAM Audio school As for acoustics...
1. Placing a speaker in a corner boosts low end a lot, but tends to accentuate troublesome room modes
2. Placing a speaker against the wall does the same, although not nearly as much
3. If the walls in your room are parallel (most are, making the room a rectangle) then you will have room modes. Particular frequencies will be boosted and cut at different positions in the room relative to each frequencies' wavelength and the size of your room.
What this means for amp placement...
1. Try not to place your amp in a corner or directly against the wall. Give it some room.
2. If you can lean your amp at an angle (many amps have those extra "feet" for this purpose), you'll cut down on the weirdness created by room-modes and give the amp a more even sound.
3. As mentioned above, make sure your distance mic is not too close.
Other things to keep in mind...
1. Experiment with Polarity if you're using multiple mics. Often your distance mic will need to have polarity flipped. Listen to it both ways and pick the one that has the most solid low end. Phase issues manifest themselves most noticeably in the lows.
2. Listen to the sound of your amp up close, and move slowly further away from it. Do you like what you hear? If the room compliments the amp sound, you'll probably want an omni or figure-eight mic for your room mic. If you don't like the room so much, you might consider a cardioid mic
3. Listen carefully and place the mics where it SOUNDS good to your ears.
4. If any of your mics have settings (Low Cut, Pad, pattern, etc.) make sure you play around with them. Often information from Guitar amps below 80 Hz (or even 120) can fight with your Kick and Bass, so it may be best to cut the lows. If you record REALLY loud you may want to use the pad on the mic.
This should be a good start...
Best of luck to ya'!