The idea is to locate the samples for soft synths on a drive separate from your audio recording/playback drive (and/or O/S and application drives) since they can take up a lot of room, and if the synth uses direct streaming of samples from disk, having separate audio and sample storage drives gives each function more data bandwidth for real-time audio streaming.
It is not necessary or desirable to separate the actual DLL files for the plug-in from the drive that hosts the SONAR application. Most plug-in installers should give you an option to install samples to a different drive, while the plug-in DLL and supporting files are installed to the default directory on your application drive.
That said, I could be wrong, but I think it's probably not desirable to put samples on a networked drive, as you're unlikely to get any performance gain from streaming samples over a network connection vs. off of a local drive, even if that drive is not dedicated to samples.
And finally, customizing plug-in layouts is done from Tools > Plug-in Manager, which I believe is included with all versions.
SONAR Platinum x64, 2x MOTU 2408/PCIe-424 (24-bit, 48kHz)
Win10, I7-6700K @ 4.0GHz, 24GB DDR4, 2TB HDD, 32GB SSD Cache, GeForce GTX 750Ti, 2x 24" 16:10 IPS Monitors