Chuckebaby - bouncing the tracks was my first thought, but as you say, it cannot be undone, sending the vocals to an effects bus is something I haven't tried, might give it a go.
He is committed though, he is even selling is Xbox1 so he can by a new PC or laptop, so that will address some of the performance issues.
Zargg71 - Good idea, I can play with a few settings there. I should have mentioned, he is using a Behringer UCA202, with a small external Sampson mixer, it is using ASIO.
I'll try your suggestions out and report back.
OT - but here is my trip down memory lane ( few newer item in there) equipment list
Synths, Drum Machines & SamplersYamaha AN1X
Yamaha TG300
Korg Poly 800
Casio CZ101
Roland D10
Roland S760 fully expanded
Control Synthesis Deep Bass Nine
Ensoniq VFX
Kawai
Cheetah MD16 Drums
Boss DR110 Drums
BOSS DR.Rhythm-220e
Effects Behringer MDX1400 Compressor/Gate
Behringer V-Verb Pro 2496 - the rare one, before they were told to stop maing them!
DBX Project 1 266 Compressor/Gate
Zoom RFX2000 Multi Effects
Yamaha EMP700 Multi Effects
Yamaha FX500 Multi Effect
Yamaha GP100
Mixers/MonitoringFostex 812
Soundcraft Spirit Folio Rac Pac
Quad 405mk2 Amp
Wilmslow Audio Speakers
MIDI & PCOpcode's Studio 64X
Philip Rees MIDI thru boxes x 2
3 x Atari STE1040
Amiga1200
Various PCs
Several older Macs
MicsMILAB LSR-3000 handheld condenser mic
AKG D90 (several)
Shure SM57 & 58
t-bone SC140 condenser mic (2)
Modified PZM, several
SoftwareCubase, Cubasis
AcidPro
Halion, Gigasampler
CoolEditPro2, Soundforge 7
Bars & Pipes
Logic
Rebirth