Good answers so far, so I'll just try to fill in a few blanks...
1. sfz files contain one or more wave files plus metadata that describes them. Think of them as "smart" wave files. To use them properly you need an sfz player. Fortunately, SONAR comes with more than one. Dimension Pro is a particularly sophisticated sfz player.
2. A keyboard instrument such as the FA08 has two sections, a MIDI controller and a tone generator. Normally, when you play the instrument you're connecting the MIDI controller (keyboard) internally to the tone generator. However, it is possible to disconnect them from one another and use them independently. The MIDI output can drive another keyboard or a virtual instrument in your DAW. The DAW can also control the tone generator separately, independent of the keyboard.
The easiest way to use the Roland as just a MIDI controller and not hear its internal sounds is to simply turn the master volume down on the FA08. All you need for the virtual instrument is the MIDI output, not the audio.
If you want to use the FAO8's sounds
in addition to your computer-based virtual instruments, then you'll want to assign different MIDI channels to each. Internal sounds are typically assigned to channel 1, and the keyboard normally sends MIDI data over channel 1. However, by assigning your virtual instrument to, say, channel 2 and instructing the FA08 to send MIDI data on channel 2, now the MIDI data from the keyboard is ignored by the internal tone generator and only the virtual instrument will respond to what you're playing on the keyboard.
3. Yes, effects can be applied to parts of a track or to the whole track. There are two ways to do this: clip effects and automation.
A track consists of one or more audio clips, and each one of those clips can have its own effects bin. This method works well when one clip needs special processing the other clips do not need. More common, and more convenient, is effect automation. With automation, you can create a graph that controls any parameter you like (e.g. wet/dry mix). It's a very, very powerful mix tool.
4. SONAR provides everything you need for mastering. However, many users prefer third-party tools, with Ozone being perhaps the most popular among them. My advice would be to learn the built-in tools first and then decide whether or not you need to invest in Ozone.
5. "Must-have" is an entirely personal opinion, and depends on your needs. Many of us consider Kontakt a must-have, while others could not care less about it. I'd really hate to lose Ozone, but is it a "must-have"? Not really. In truth, I cannot think of
anything that's a literal prerequisite to making records beyond what SONAR gives you.