Compressors are the opposite of what’s needed to boost transients compared to the average signal level.
A transient shaping plugin after the sim might help.
Lack of transients in guitar setups is often due to using too much gain/distortion which compresses the signal too much. The problem I’ve found with sims is that they simply don’t respond (or sound) like valves do, or like transistor fuzzes, distortion pedals etc. do either.
My “silent recording guitar” setup is an amp (currently an Orange Rocker 15 Terror head) into a Palmer speaker emulating DI and load box and a few good pedals. Sounds and feels very convincing. As does the same amp on it’s lowest power setting which is around 0.25-0.5 Watts. Some of the small sub-1Watt amps are worth considering as well, e.g. the Blackheart one. The Blackstar one is popular as well, but much too noisy for my tastes.
The Sansamp Character series and Flyrigs are also worth taking a look at. For a bunch of solid state circuits they do a good job.