It's natural for the 'main' core to be using a lot more processing power than the others, because it's not easy to distribute the work evenly across all of them. An i3 is pretty weak these days sadly, so you may just be reaching the limit of what it can effectively do.
You might benefit from increasing any buffers, so that the plugins in each of the secondary threads have longer to operate before they have to rendezvous with the main thread.
Also, if there are any plugins that can be split into multiple instances - eg. Kontakt or Play with multiple instruments loaded - consider doing that, to spread the load more evenly.
And don't forget that you might be able to freeze certain synths, which takes them out of CPU usage altogether.