For your system drive using the SSD drive, yes, boot time is very quick, and opening programs is faster, that's all.
To utilize your other SSD drive, it would be most beneficial to have it as a drive containing your sample libraries, rather than merely hosting Sonar projects. Samples will load faster. How large is your extra SSD drive ? If you have really large sample libraries there's always the argument about whether having a decent 7200 rpm sample drive vs. a large SSD drive for samples will get any performance increase, because the large SSD drive costs so much more.
Once the samples are loaded into RAM, is there any increase in performance ? . . . probably not. The question is, do you have time to wait a few minutes for large sample libraries to load from a 7200 rpm drive ?