I had some similar issues but with different hardware. Try disabling any audio drivers that aren't associated with your hardware.
In use by another program would indicate that your driver setup is being hijacked either by onboard sound or another device.
If you have a need to use dual devices this might not be a the best option. If the secondary device is using WDM drivers and you want to use ASIO drivers there will likely be a conflict. In some way there needs to be a device selected as the main audio device and it apparently isn't the VS-700.
Right clicking on the speaker icon should show you the available devices and which are in use. Both recording and playback devices can be selected independently.