Since you have already move the data
SampleDataDir was pointing to, fix the registry entry to point to the new location. If you kept the "Cakewalk Content" directory structure and moved the entire thing over to G: the new
SampleDataDir value be "G:\Cakewalk Content\Cakewalk Sample Data"
If the multisamples were not kept in "Cakewalk Content" then set
SampleDataDir to the path holding the "Rapture Pro" multisamples folder. Do not include the "Rapture Pro" folder in the path, it must be the path containing the folder.