Before you spend any money just try it in Sonar and see how ASIO presents the 2 devices. Sometimes the driver does the synchronising for you. What you do need is for the driver to show you all the inputs and outputs of the 2 units. If that doesn't happen then synchronising the clocks through SPDIF or an external unit like the ART Syncgen won't matter.
You may be able to get it to work under WDM/KS. It always depends on how well the WDM drivers are written. WDM does allow for multiple drivers and devices being addressed simultaneously, however you may still need to do external synchronisation. Just try the software routes first.