Full Kontakt comes with a Change Keys script you can assign to instruments or the entire multi (not sure it works for player only). It lets you map any key to another key. So you can create an alternative set of keyswitches that trigger the real switch. But it won't change the color display/relocate the key, which might confuse you a lot. Depending on the instrument you might find there isn't a good place to put the switches though.
Look under Factory->Transform->Change Keys for the top level KSP (you apply a top level effect by pressing the KSP button at the top of the Kontakt UI) and Factory->Randomize & Change->Change Keys on the instrument level (press the Wrench, go to the Script tab, find a blank slot and look under the presets).