Thanks everyone for the helpful comments, I've done some more testing and made a new user account on Windows as I've been struggling with some other things too. Certainly has helped in the project load times, the opening project bar now appears straight away instead of sitting with not responding for a long time.
So just about to re-install Windows 10, pretty sure the only things I have altered were things from a guide on here for preparing PC for DAW, I know each case is unique but I'll see if I can find out why the hangs and report back.
The long painful re-install process ;(