A good technique is cut volume when mixing. Keep in mind as tracks are summed at the master buss there is going to be a volume increase. I like to lower all faders when I start mixing. I bring each one up as needed as I work on each track. Over time I may need to readjust faders so a track sits right in relation to other tracks. Automation is very useful here but should be applied after most all other levels are well set. Otherwise it will need to be re-automated.
One shouldn't worry too much about the final volume when mixing. That should be a concern when the mix is well on its way to being finished. I like to master a stereo file of the mix not the mix itself. I don't mind going back and redo a mix if the mastering is not working. Mastering should be simple and easy. If it isn't a remix may be needed.
With Sonar's Mix-recall Sonar has taken a great leap forward for being able to judge different approaches to mixing a song or project.
Also try the mix as a mono mix. See if it has all its frequencies and they are in the proper relationship as the stereo mix. If you loose an instrument in the mono mix its mixed wrong.
Levels when recording are not as much an issue if done at 24 bits. 16 bits will need careful monitoring to have a good level without clipping. 24 bits is very forgiving and will save a lot of hard work in the long run.
The above are a few tips in basic mixing.