I'd say this about
any LA2A emulation, or the real thing itself: It's a design that's great for stuff that's not very attacky. So great on vocals, great on non-twangy bass, can be good on organs and pads. Less useful on guitars, drums, pianos, etc, unless you're after a noticeably non-transparent compression.
For the CA-2A, I'd have to check, but I think it's the only compressor I've used on vocals for about two years now. I rate it
very highly.