Kamikaze
cparmerlee
jpetersen
The first secret is, each instrument takes a different note in the chord.
That really depends on what genre you're trying to capture.
Chicago was/is mostly unisons with occasional breakout chords on the longer notes.
James Brown was mostly triads 3, 5, 7 or 3, 7, 9. Often inverted with the 3rd on top.
EW&F and BS&T used WAY more color tones, more like writing for big band. Never use a root or 5th in those voicings. Most of the horn chords are guide tones (3rd and 7th) and color tones (#9, b9, #11 & 13 e.g.) And BS&T used a lot of half-step rubs in the middle of the chords.
ToP was less about the voicing and more about the rhythms and energy, but you must have bari sax on the bottom for that sound.
and so on.
It is also important to consider the register. Chicago likes to put the trombone at the top of the range right with the trumpet instead of an octave lower.
If you ever get a chance to expand on this, that would be fantastic. I'd be interested.
If you have a particular band or song in mind, I'd be happy to give it a listen and make more specific comments. There is a lot of variety to how horns are used, so it is better not to generalize too much.
Some of the funk stuff was heavy on voicings that internally have major 7ths, which can work like those half step rubs and may be a little more pleasing to the ear. (The half step stuff is intentionally grating, and best used for tension in the middle of a musical line, not at the beginning or end.) The most common of these, I believe, (especially in funk and blues) is the 7(#9) chord. You put the major 3rd in the low octave and the #9 (which is the minor third) in the octave above, and usually the 7th in between. In a C7(#9), that gives you, e.g., bone on E, tenor or alto on Bb and trumpet on D#. The bone and trumpet are a major 7th apart, giving this really strong tension.
A similar thing can happen on the 13 chord. You put the low voice on the 7th, middle voice in the 3rd (in the higher octave) and the top voice on the 13th (which is the 6th an octave up.) In a C13, you could have bone on Bb, sax on E, and trumpet on A, again putting the trumpet and bone a major 7th apart. You normally want to use these strong voicings on longer notes. If it is just a passing note, the audience won't really get the effect and the horn players probably won't really milk that tension.
These voicings aren't just for horns, of course. You can hear a good example at the beginning of EW&F's "Yearning' Learnin'" That tune is loaded with 7(#9) and 13 chords with open voicings.
Another thing to bear in mind is that if there is a strong root, then the listener hears the 5ths without anybody playing it because that 5th is a primary overtone of the root. That's why guitar "power chords" are so strong, because they are nothing but root and 5th, and the overtones reinforce that interval. So you can usually leave the 5th out of the horns if you are writing for a genre that is harmonically sophisticated (jazz, or some of the hipper pop stuff like Steely Dan).
I guess the point I'm trying to make is that, while the samples are important, if you want the thing to sound like a horn section, then you need to write the parts as a horn section would play them, and that varies a lot. The more successful horn bands had some very distinctive writing styles for their horns. You can't usually just write simple triads and call it a day (although that may work fine on stabs.)