sorry, I didn't realize you intended to record the MIDI first.
if that's the case, then what I would do in order to eliminate latency is this:
connect the Roland up to the computer using USB. set up a MIDI track in MC to record that roland MIDI input
connect the Roland's MIDI output port up to the Ketron's MIDI input.
connect the Ketron's audio output to the behringer (again, I do not recommend using the RCA ports for this - use 1/4" connections to one of the main stereo inputs)
send the output of the behringer to the speakers.
there is no need to connect the behringers' USB connection to the computer at this time, nor do you need to set up an audio track in MC to record anything at this time. currently you're just going to record the MIDI, but you'll HEAR the ketron output directly with no latency as you hit record and begin playing the roland.
after you've created the MIDI track in MC, you may edit it as you desire.
then you need to connect the Ketron MIDI OUTPUT to the computer. this might require additional hardware you don't currently have. you'll need a MIDI to USB cable to do this. something like this could work:
http://www.amazon.com/HDE-Synthesizer-Microphone-Instrument-Converter/dp/B00D3QFHN8/ref=sr_1_6?ie=UTF8&qid=1447854681&sr=8-6&keywords=midi+usb+cable beware, MIDI/USB cables which are cheap may not work well. I paid $30 for my first one and it worked well. others who paid less for cheaper models have not had as good luck.
so connect the ketron MIDI output to the cable and the other end of the cable to the computer via USB.
now set up an audio track in MC to record the input from the USB cable coming from the ketron.
set the OUTPUT of the MIDI track you just recorded to the INPUT of the ketron via the ketron USB connection
arm the audio track and hit record on the transport.
this will send your edited MIDI to the ketron and will send the audio from the ketron to MC and record it on the audio track without latency.
this will work regardless of your latency buffer settings in your soundcard.