From my own point of view, 24/192 is a bit over the top, as too is 24/96, but I can certainly here the difference between 24/44.1 and 16/44.1. As one poster has mentioned, if you use a lot of saturation plugs, the more you have to reduce bit depth...the more distortion becomes obvious. Not the wave file mind you, but when you convert it to Mp3 you can definitely hear the problem. This is a larger problem though, within the misunderstanding of the digital medium and the analogue emulation aesthetic. If you understand the digitized medium properly, and it is used properly i.e. 32bitFP or 64bitFP, as well as, when the audio gets digitized the signal cannot be fed out of the box again for further processing, because this is where a lot of the problems occur, and is the only reason you would need boutique and expensive converters, but so long as you understand this, and understand the sweet-spot theory in regards to real world and virtual processors...digital far surpasses analogue. This is one of the reasons why I bounce out all my final masters as 24 bit now, and then convert them. When I listen on my phone, its all 24 bit wav files too. There is no reason not to use 24bit files now, because storage on our devices can handle larger files.
The other thing that needs to be mentioned is the obvious difference in time based effects and 96k, it's the reason why there's a switch for that in Sonar...if you listen carefully its in the tail, the difference between 44.1 and 96k. It just sounds nicer. I also like 96khz for recording anything acoustic, there is obviously more air, but I always convert the signal to either 48 or 44.1 for general listening.
Ben