Are you saying you have the stereo input connected to your Asus sound card output?
If so, that won't work if you are using the ASIO driver for the Duo-capture.
ASIO allows only one sound card/interface to be in use.
The Duo-capture is not just an input device, it is a sound card/interface.
You need to connect the stereo input to the 1/8" Line Out (not the 1/4" headphone out) of the Duo-capture.
You will most likely need an 1/8" stereo x 2 RCA adapter to do this.
In GTP, make sure the Duo is set as both recording and playback timing master in Options>Audio.
If you have ASIO selected, the Duo should be the only device available.
Set your bit depth to 24, and your sample rate to 44,100.
That should get you going, but let us know if you get stuck.