I think they are great and the can solve a lot of issues sometimes. I like them in mastering. You can get away with a full range compressor on most things on tracks due to the nature of the sound being less complex. On full mixes multi band compressors can be better.
A couple of things worth doing with them though. It is good to solo the bands and hear what areas you are effecting. I find it helps. Also be prepared to alter the crossover frequencies. Don't just use stock settings because I have found altering them can give quite different results. Solo the areas while you are setting crossover frequencies too. Smoother more transparent operation results when tweaking the crossovers and bandwidths etc.
The multiband can tame just a certain area of your mix well. It can also when confronted with a real nice mix just dance over all the bands and then it is nice to get all the bands doing equal gain reduction too. The sound or EQ won't change. You can still get into light conditioning over a well mixed master. Small amounts of GR eg 1-2 dB, slow attacks and low thresholds like 1.5:1 in most of the bands. Release settings are important too. It can impart a pro sound to your master.
It's cool to be able to alter the make-up gain of each band as you can turn it into a sort of nice active EQ as well. I find I can use less mix EQ
(pre compressor usually for me) using the make-up gains in the bands instead to fine tune a mix EQ.
It is nice to be able to alter the ratio and GR of any given band. And then all bands locked together at times when making adjustments but also you have to fine tune bands individually too for best effect.
I like the Sonar Multiband a lot as I feel it shows you a lot of information in one look. The Studio One multiband is a bit complex and it frightened me off at first but after a while I got all over it and it is excellent as well. Mixbus has one of the best though. What that can do is limit the amount of gain reduction ie it can be set so it never drops below a certain level which is actually great. Eg -2.5dB etc Even on a loud segment, instead of a band dropping way down by crossing over a threshold with a large amplitude, it still does some GR but then stops at some point. Overall mix EQ can be maintained well that way. Some of the dynamic range is left in any one band. That is a cool feature, some multibands can’t do that.