Absolutely but you would be best using 2x mono 1/4 to rca and connect the 1/4 in the SUB output. This way your signal will stay unbalanced all the way.
Be careful, cause Windows tend to set the MAIN out as default, so switch that in the Windows audio mixer (near the clock in the lower right side).
If you absolutely must use an XLR to rca, make sure the pin 3 (cold) on the XLR jack is soldered to pin 1 (ground). You can do it yourself pretty easily if you have a soldering iron and some experience or know someone who does.