SOLVED!So I figured out what my problem was. My new motherboard has a Realtek S1220A audio chip onboard. I had disabled the on-board audio in Device manager. I could see references to Realtek ASIO in aud.ini, so I deleted it and restarted Sonar, again it crashed, but when I looked in the newly created aud.ini, the reference to Realtek ASIO was back, so disabling it in device manager was not stopping Sonar from seeing the drivers. So, I uninstalled the device in device manager, choosing to remove the drivers. I deleted the aud.ini again and this time Sonar launched without crashing. So, to make sure it didn't come back on next boot, I went into BIOS settings and disabled the Realtek audio device there too. I rebooted and again, Sonar launched just fine. I was then able to select my MOTU audio I/F and all is now fine.
So lesson learned - disabling a dodgy onboard card in device manager is not enough - you have to get rid of all traces of it.