I'm repeating a bit of what's already above, but there are a couple ways to achieve this, depending on what you're looking for.
Since your originating instrument (guitar) is mono, just converting the track to stereo may or may not give you the desired result you're looking for.
Another option is to record it once (in mono), clone the track you just recorded and pan the two resulting tracks left and right. Bear in mind, this won't sound any "fatter", as it's the exact same signal, just taking up a wider portion of the stereo spectrum, and it will sound louder, since you're adding more of the same signal.
If you want a 'fatter' sound, take the advice that Soundwise gave above - record your guitar two separate times on two different tracks, then pan those tracks left and right as wide as you want. Not only will this give you the wider / stereo sounding guitars, but it will sound much fatter than just cloning a single mono track and panning it similarly.
Hope this helps.
Russ