Cactus Music
You'd haver to upgrade your entire signal chain to hear that 0.2% improvment in sound quality your going to get.
I am afraid you are perpetuating the myth that makes 96 K attractive to so many. It is absolutely not the case that 96 K samples per second improves the sound quality over 44.1 K by any percentage. What increasing the sample rate does accomplish is to enable the accurate encoding of higher frequencies. Since 44.1 K sps is more than twice the 20 Khz frequency that represents the upper range of human hearing that represents the best sound quality that can be heard. While 96 K sps will enable you to accurately encode a 48 KHz tone, it will enable you to extend the frequency range by more than 100%, but no one can hear it.
Although there are endless discussions about oversampling, aliasing, foldover and ultrasonic interference, that may be relevant in designing sampling interfaces, there is no way to put a percentage improvement on the "quality" of the sound produced by setting your store-bought interface to a higher sps.