One thing that is often overlooked is how are we defining "sounds better" when comparing instruments?
How is a fair comparison to be made? The bottom line is the perception and intended use by the end user.
Are we judging the samplers and synths in the same way? Based on what? Sample quality, factory presets, sound source (sample playback, analog modeling, physical modeling), the sound architecture, the available expansion packs, the ease or depth of programmability?
Some folks just want preset sounds to quickly set up an arrangement. That's fine. Others may want to develop their own sounds and presets. So they want more capability under the hood. Different styles of music have varying sonic expectations. I doubt there is one instrument that meets everybody's needs. Just look at the sheer number of the available plugins and libraries. None of them sound inherently bad. But there are good and bad patches everywhere.
That said, I like Dimension Pro, but I wouldn't buy Platinum just for that. I don't think that Dimension was ever intended to compete with the other commercial sampler libraries, but was intended to provide a starting point for creative sound design. It came with a library as a bonus. It is unique. It's a synthesizer that uses samples for a sound source.
But the synth technology that RGC audio (Rene Ceballos) developed, which was bought by Cakewalk, is a good one. It underlies all of the major Cakewalk synths - Triangle, Square, Pentagon, Dimension Pro, Rapture, Z3TA+ 2, etc. The original RGC audio z3ta+ is still considered great by many. I think Rene was possibly way ahead of the current pack of synth developers.