I looked into that just now and I'm finding sources that are telling me that SPDIF is routed through outputs 9 and 10, which does make sense since it's normally an 8 channel device.
I'll have to look into that when I get back into the studio tomorrow. Thanks for pointing me in that direction, I'll let you know if that solves it!
-Edit
Just got back to the studio and it does appear that for whatever reason, the Presonus Firestudio labels the SPDIF out as analog 9 and 10.
Thanks for pointing me that direction!