I honestly believe that mixing and mastering cannot be done at the same time. Personally I feel it is a big mistake. After a long mixing session there is no way you can make rational decisions about mastering processes. It is actually pointless to do so.
(Especially if you are mastering your own work) Do your great mix and then burn that to a CD and wait a week. Listen to your mix quietly here and there. In the car, on other systems etc. You will start to pick up little things about the mix that are not perfect. Something a little loud here and there, entrances and exits, too much clutter going on in one spot etc...
Then setup a totally new and fresh mastering session. (No extra buses required) You will always get a much better master doing it this way. You ears will be fresh and it is like hearing it all again for the first time. (Something a third party mastering engineer gets to experience)
What is the hurry? If you want to do something really well, it will take time. Some people say around here you can do it at the same time but if they used this approach they would always master better. Simple as that.
Even back in the old days when famous mix engineers were forced to master straight after a mix session in order to get the record out to satisfy the record company they most often said later thay regretted doing it that way and they would have mastered it differently. I have read that so many times in interviews with some very well known people. Listen to what they are saying, not just me!
To the OP I know this does not help you and I apologise for that, I am simply trying to make you rethink your strategy. Often that removes the need to solve a technical issue eg setting up multiple buses at the time of mixing.
I can almost guarantee that if you wait a week to master you will:
1 Use far less EQ on the overall mix because your ears are not tired and you can
really hear what the EQ is actually like
2 Use less compression and you won't be slamming it anywher near as hard. Slower attack, gentle compression only.
3 You won't be pushing your limiter as hard because your ears are also not tired and you will find you can get the limiter pushing overall levels up without working too hard at all and you won't hear the limiter either. (changing our sound that is)