The sound quality of the Amplesound guitars, and the articulations available IMO is second to none.
I heard a demo of the acoustic version of Hotel California, complete with solo, with 3 of these playing and it blew me away.
Getting anything near to that realism however takes a LOT of learning and patience... like hours of tweaking until you get exactly the sound you want. So be prepared to be disappointed if you don't get immediate results.
I actually find it quicker to just play it for real, and accept that my old Crafter acoustic isn't a Taylor or a Martin.
What I would say though is if you record a real guitar first, it's much easier to "copy" that performance in Amplesound, simply because you've got all the nuances there to reference. This still takes a long time, but it's a lot easier to imitate an existing part than trying to come up with a realistic part from scratch.