Do they make such an audible difference? I don't mean when recording subtle acoustic stuff at 192khz, but, in everyday life, for rock and roll and heavy music.
The best I had were probably the ones on my old M-Audio Delta. However, my monitoring system back then wasn't really allowing me to enjoy subtle nuances.
As you know, I have yet to replace the Fast Track I grabbed before we left for the tour and I suspect that the converters are pretty average. And the preamp, well...

But it worked as expected.
I also remember reading something back in the days that basically said that, usually, the higher the sampling rates the audio interface could handle, the better the conversion was even at lower sampling rates.
I've been looking at Focusrite, which appears to have decent converters and good preamps. But I might also have the opportunity to get an Apogee duet. It would fall short of providing me the 4 outputs I'd like, but I can always compensate by using a little mixer as a patchbay.
W/ Christmas coming, I've been doing some serious online pre-shoping and Apogee sure gets a lot of praises for its converters and preamp. And since the audio interface will probably be the first thing on my list...