NRC ratings exist to simplify things for builders, and aren't referenced much by acousticians, who consider them obsolete, inadequate and largely irrelevant for studio applications.
There are two main limitations to NRC values. First, they don't even bother measuring below 250 Hz, where your biggest problems lie. Second, they don't take into account the thickness of materials, only surface area. Fine for picking out ceiling tiles for your office, but not very informative for studio treatments.
An NRC rating of 0.65 might sound impressive, suggesting an absorption efficiency of 65% and clearly beating out drapes and carpets. But it's only half as effective as a 4" 703 panel of the same height and width. Yes, proper absorbers will have an NRC rating greater than 100%.