If he has the latest updates installed, your friend has his answer there - OSX 10.6.8 and later require
2 GB of RAM.
How many times must Alan Parson say it? RAM is everything!! :P
Anyway, unless he is running out of HD space - which of course might affect performance, I don't see how those movie files could affect performance.
Other than that, the basic maintenance can't be bad - verify/repair disk and verify/repair permissions.
Defragmenting on Mac isn't really as crucial as it can be on the PC. But ultimately, considering that it's an older machine and that it's been in use for quite some time, it might help a bit.
For DVD burning, Roxio Toast is probably one of the most common. However, from my personal experience, even though I rarely need to burn DVDs, the default Mac DVD software works just fine.
But unless he adds some RAM, I doubt that anything could really help much.