$30 an hour for getting yourself out to the gig and capturing the waves should be reasonable IMO. That's the real pain in the butt. You have to put up with drunks, put your gear in a toxic bar environment, wrangle with routing/cabling/the house PA/etc and transport the gear back and forth.
Mixing? IDK... if they were demanding the finished product ASAP I personally would charge more than if I were allowed to poke away at it casually. If I could do it within my own timeline and they weren't super finicky (minor adjustments... not total mix overhauls) or insist they come by all the time and involve themselves in the process (I do not like people hanging around) I'd probably just give them a flat rate of like $100 or less for an albums worth of stereo waves at pre master levels and another set that I "mastered" myself for immediate consumption.
If they WERE going to crawl up my butt during mixing/editing I'd probably charge $15-20 (seems like reasonable semi pro demo rates) or more likely tell them to find someone else if they were particularly annoying.
I however probably won't attract very many clients for quite some time and frankly I'm okay with that. I have my own music to make.
/not a pro