Do I need a DI if I have a condenser mic? Or should the mics pick up the guitar well enough so that I don't have to turn the input levels all the way up?
input levels are a different issue.
no matter what the source, you always want to achieve input levels with the same goal in mind:
a great capture.
you don't want 'overs', but you also don't want a weak signal that might raise your noise floor....
you should always set INPUT LEVELS for their OPTIMUM SETTINGS
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what is that setting you ask?
well, that's the name of the game, really....
getting to know your equipment, where 'OPTIMUM' really is, and figuring out how each element of the recording chain works GAIN STAGING wise.
after that, it's all about the source, and the TECHNIQUES for capturing the source.
if the guitarist LIKES the sound of the pickup in his guitar, then use it...
but also add in a decent microphone (the choices are huge) and blend them together, favoring the mic over the direct sound.
even the way you blend these together, is a critical element in making the guitar sound... perfect.
you gotta experiment, but look at the basics first.