This is encouraging. I don't think I can help Ston make an amp from engine parts. All the valves I know about are glass. As for why there's nothing new being developed, well, making tubes is a dirty, nasty business. All of the production is in eastern Europe, Russia and China. Back in the day, they used to be made in America, England, Holland and Germany.
There are a lot of toxic substances that go into the coatings used to treat the cathodes and plates. Things like arsenic, cadmium, lead (sometimes in the glass) and other heavy metals. Most of the assembly is done by hand. In order to be profitable with tubes (valves) you need a lot of cheap labour and lenient environmental regulators. (In my opinion)
There are still some industrial applications that require tubes but it's mostly hi-fi and guitar amps now. Low voltage designs are beyond me. If there's interest I could post something on how tubes actually work. At the heart of it, the principle is one of differences. You have to have a high potential at one end and low potential at the other. This pulls electrons from the low side to the high side. A third potential is applied between the high and low to regulate the flow rate. This is where the term valve comes from. Trying to do it with low voltage would be tough.
I pick valves for my design based on availability, so I only use valves that I know folks will be able to buy into the foreseeable future. There are hundreds of different types on the market but most are no longer in production. This is an important point if you come across old amps. You have to avoid out of production tubes unless you know enough to rewire the sockets.
I know how you are supposed to post links but so far no luck. There's some sort of security thing going on with the drop box that I have to sort. Right now I'm building a newer design I call the Producer 88. It's a 15 watt amp running a single KT88 for the output. It has a simple 3 band EQ and is designed for the needs of a small studio. It will be documented in a series that I'm doing for thetubestore.com and posted online in 2 or 3 articles. I've helped them with reviews and articles for a number of years. You may find some interesting stuff on their web site.
If you have any amp related questions post them in this thread and I'll try to answer them. Remember, I know NOTHING about solid state. It's voodoo and I avoid it.