If you want mostly clean, then at 5 watts the Epiphone Valve Junior is pretty good, apart from the supplied speaker which, unless they've changed it from the one in mine, is very cheap and quite nasty. Switching it for a 4 ohm 8" Jensen makes a big difference. Nice clean sound, though no tone control, and well built for the price. Overdrives nicely when cranked a bit. Same applies to the old Fender champs of course, but on my side of the Atlantic they are quite rare and expensive (even rarer and more expensive if they're any good) so I've no real experience of them.
At really low wattage the Blackheart B1H1 takes some beating, especially at the price. Uses two 12AX7s in a simple, well made all valve circuit. Output's around 1/4 watt flat out and it breaks up into nice pick-sensitive power amp distortion at comfortable domestic levels. Again, no tone controls but the preamp circuit is essentially a Marshall JTM45 with bass/middle/treble all flat out, which gives a slightly mid scooped sound. Power section is half a 12AX7. Works very well into a ten or twelve inch Celestion greenback in an open-backed cab for a Hendrixy, 60s/70s "British" sound and feel. It gets a bit bass heavy for me with a closed cab.
Going up on power, the (7 or 15 watt switchable) Orange Tiny Terror covers the plexi-ish/Orange end of things very well, and the 15watt setting is pretty loud if you need it. Can handle gigging about the same as a Femder Deluxe. Even the 7 watt setting is pretty loud. No issue with re-biasing the Terror when changing valves either, as it's cathode biased similar to the Vox circuit. For my money the Orange is a better and more flexible amp than the AC5 or AC15.
If you're looking for an amp for low volume domestic/practice use remember that a 5 watt amp will deliver about half the volume of a 50 watter running into the same speaker. 5 watts is not quiet, it will give a trumpeter a run for their money and more than one live sound engineer has complained my Tiny Terror at 7 watts is "too loud". So picking a 5 watt amp that needs to be run pretty much flat out to get the sound you want may not be an option - master volume amps have a role even at low wattage.
Other than that, it really comes down to what you want to spend and what sound you are aiming for. There are hand-wired small amps that are superb but with prices to match. Not got one myself, but having played through one I rate the Fender Clapton Champ with tremolo as excellent.
Final thought - go for simple, basic valve (tube) amps if possible. The solid state/modelling stuff isn't the same unless you want brutal mega distortion with a huge mid cut :-)