I'm a country guy, owned this CD since it came out, listen to all of these players (a ton) over the past 30 years, and I can't tell them all apart - not for certain anyway.
The only one that I can pick out (with at least 99% certainty) is Albert Lee. He plays so far ahead of the beat that some would argue is "sloppier" than the others, but that's the magic. The best description I have ever heard regarding Alberts playing is from Guitar Player Mag. "... sounds like a trainwreck the never derails!"
Here are the sections I am positive are Albert:
:51 - :58
1:57 - 2:03 (< although this could also be James Burton. The more I listen, the more I think it's James)
2:55 - 3:02
Points about the other players.
1: James Burton will sound like a tame Albert Lee. Albert used to listen to James Burton a lot, and expanded on his approach.
2: Albert Lee became the quintessential country player, definitely the one most copied! They ALL play a little like Albert (which in turn means they ALL play a little like James Burton as well)
3: Vince Gill sounds like a "perfected" Albert Lee. His timing is impeccable, tone a little tighter, 95% the same licks!
4: Steve Wariner will be the part doubled with a vocal! (1:34) This was his trademark style. I'm sure he is scattered elsewhere - but I can pick that part out :)
5: John Jorgenson will play a little dirtier, and is likely the one playing the "delayed guitar lines" at 1:42. John was a key part in the Hellecasters and also played with Elton John for many years. I think it is John at 2:33 as well! That sounds like him with the Hellecasters - slugging it out with Will Ray and Jerry Donahue!
6: Redd Volkaert! I used to watch him (even got to jam with him a few times) in Saskatchewan and Alberta during the early/mid eighties when he played with Danny Hooper out of Edmonton. He's always been a monster, but I seriously cannot pick him out on this recording. He was the master of Roy Nichols style (Merle Haggard) and that is likely why he landed a 5+ year gig with Merle and The Strangers.
7: Brent Mason. The best studio guitar player Nashville has ever seen! Problem is - this guy can sound like ANY ONE OF THE ABOVE (to perfection) so that makes all bets off on who's who - LOL!
As for Brad Paizley himself, he's playing the head (first 45 - 50 seconds) with a few licks scattered throughout! Great player, and actually has Alberts ablity to "trainwreck without derailing"
Most of the guitars would be TELE's or Fender Custom Shops (with a TELE bridge p/u)! I'm not hearing anything here that says otherwise. Even Steve Wariner who quite often plays a strat sounds like he is on a Tele on this recording.
Thanks for posting this Mike. I love it when "country" gets a nod of approval and others get a chance to hear there are real "cats" in that scene!