Always check the back of the midi unit (keyboard). Usually they will have both - 5 pin din for midi (regular) and USB.
Check everything, because some USB on a keyboard may be for only downloading to another program to change the patch sound and upload it again from a program that runs on the computer. The regular din MIDI connection is the normal one, and while some support USB, if you could record at 96000 sample rate and 24-bit with ASIO drivers in the audio/interface, the USB probably only records at 44.1kHz sample rate or 48kHz sample rate at the most and there is no way to record at 96kHz sample rate. Usually most are still only 44.1kHz sample rate (at least on my units say for guitar - guitar effects box unit or the USB like said is used for changing sounds only like mentioned. (I use the line outputs on my guitar boxes to record at any speed since they either go to a mixer or an amp and can be used to record with also).
Not all keyboards have full midi implementation and others do, which may make a difference in the end also. (only subpart midi implementation). Yes I know it costs more, but there is used equipment to buy also.
http://www.gearslutz.com/board/ And as for anything else, the Peavey6 can be used and plugged into say a Focusrite two inputs (left and right) and also the ART unit (if stereo) or probably even both plugged in like the Peavey to the ART to the Focusrite, as long as the inputs on the Focusrite are not overloaded, any combination can be used or no combination and just the Focusrite.
If used equipment for the audio/interface (or even new equipment) make sure the drivers are for current OS's and are good to use. Some really older equipment may be there to sell that drivers were not updated for newer OSs on a computer.
Not good then.