Starise
Magix has some very reasonable pricing.
I bought Kontakt Komplete Ultimate not long ago. It's full of both synths and sampled instruments. There hasn't really been a reason for me to look anywhere else. I've been steadily buying Kontakt sample libraries here and there to the point that 99% of all sound bases are covered. Aside from playing real instruments it doesn't leave much to be desired.
I also bought several of the stand alone synths. The Korg M-1 and similar.
My most recent surprise was buying Hybrid 3. I picked it up for 12.00. I didn't expect much. I'm really impressed with it. As it turns out AIR music technology is a direct competitor to Native Instruments in Germany. They either were or are major contributors to the synths in Pro Tools. Since then they have branched out to sales for everyone.
Their UI is very easy to grasp. I'll probably buy the rest of their synths the next time I see a sale.
It sounds like you are all set for sampled instruments. But I agree that Hybrid 3 is a nice synth. I got it with the AIR Instrument Expansion Pack 3 upgrade, which as far as synths go, includes that plus Loom and Vacuum Pro. Lots of useful presets in all of them, and together they cover hybrid, additive, and subtractive synthesis.
That upgrade bundle is good if you own any single AIR instrument. It had been on sale for a long time until recently for $74.99, but I just noticed it went back up to $149.99. The best price I see now is at Audio Deluxe for $125.99 with code APR2017.
The Structure sampler has 37 GB of good samples, and the Strike drummer is a fun virtual drummer, with total control of performance and mix settings. The Velvet and DB-33 are good digital piano and B-3 organ emulations.
All in all it is a worthwhile package for the cost. Hopefully the door buster sale will happen again at some point!