I wouldn't regard the 2i4 as an upgrade on the same level maybe (assuming it has exactly the same inputs and outputs). Couldn't you have bought a FireWire card to plug into your new motherboard?
Anyway I assume you have the latest drivers. With ASIO drivers the current behaviour you describe is generally the norm however as you say the saffires somehow bypass this limitation (the drivers are fantastic).
I'm not sure about 2i4's you will have to wait for further comments or contact focusrite. Have you checked the sound settings under windows? (Control panel - Sounds).
The workaround if not possible is to use your internal sound chip inside your motherboard if it has it or buy an additional sound card for your windows sounds (or buy a FireWire card for your saffire then you could possibily run both, you will probably get slightly better performance with the saffire although there's not much in it) .