First install the latest 64bit drivers and then run the wave profiler and set up the MOTU in Sonar.
I'm assuming you researched and this card has valid 64bit drivers.
Also, if the project is not recorded in 96kHz orgianlly, you cannot play it back in 96khZ. Sonar projects are locked to the sample rate they where recorded in. you would have to export every single track individually to 96kHz and then import them into a new project for it top play at 96kHz