Your system will be plenty "robust" for running 8.5.3
XP is a great OS; I engineered a full band session, 12 mics on the kit, bass, 2 guitars and scratch vocal,
with a similar system, it was X1, but 8.5.3 would have been fine.
My office rig (it is Win7x86) "sees" 3.37 gigs of RAM with 4gb installed.
I'm pretty sure my 4 gig XP system (not a DAW) reports about the same; no "tweaks" just PnP.
i7, x64OS (Win7 or 8.1), 16gb+ RAM; awesome! Necessary; hell NO!
You'll be just fine, way more power than ANY studio in which all the "classics" were recorded.
ENJOY!
Tom