One thing when planning a guitar emulation with synths is to remember and accept that you're faking.
Don't expect to get realistic
and impressive sounds, settle with somewhat impressive and very usable. Pick a decent guitar sound, even a dry one, from some synth, and start playing with amp simulators and FX. Don't put it too much on the top, because it's weaknesses are then too audible. When the part sounds at its worst, hide it a little into the accompaniment or distract the listener with a cymbal or something, and push the best parts gently forefront.