Dave,
dBm is a measurement of power level relative to 1 milliwatt.
dBu is a measurement of voltage relative to the voltage that would produce 1 milliwatt into a 600 ohm load (=.7746V).
So if we are always expecting a 600 ohm load then dBu is equivalent to dBm. Most often, you will not actually have a 600 ohm load (it will probably be a higher impedance). What that means is, if the specs you quoted are correct, the unit will still be able to output a maximum of +21 dBu, but the output power needed will be considerably less than the maximum the unit is cable of (+24 dBm).
I would guess the reason for the difference in the max dBm and max dBu values given is that they are saying that the output drivers are capable of producing a power level of +24 dBm, but as you increase the input signal level, something else internally will cause the unit to clip when the output reaches +21 dBu and above.
BTW, +21 dBu is plenty of output level to drive any DAW input.