Lots of good advice here.
One of the benefits of the Rane and Stewart headphone amplifiers (and if I may pat myself on the back, mine too<G>) is that the front end includes a proper attenuator, so that you can drive the distribution amplifier from any reasonable source - +4 dBu Line, -10 dBu Line, or even a headphone output. You can't do that with the Rolls, or a lot of other inexpensive devices, they are designed to be driven from a line level output. In some cases a specific line level output.
It's still better, in general, to use a line level output because headphone outputs are designed to drive headphones, not line level inputs. I did build a headphone level input into my little headphone amplifier, but I eventually scrapped it, since it did not seem all that valuable. I'll have to re-think that if I decide to make it a product!
The splitter cable thing will work with a well designed headphone amplifier. You will reduce the power delivered to each set by half (3 dB), but often times that isn't a big deal. The issue to consider is that an amplifier will, of course, deliver all the power it can, and when you exceed that the amplifier goes into a condition known as current limiting, which is exactly what it sounds like. The power supply that powers the headphone amplifier can provide X mA of current, when the load on the amplifier exceeds that the power supply rails start to dip below their rated voltage, and things can get really ugly from there.
This is LARGELY dependent on the headphones in question. When I designed my headphone amplifier I surveyed a bunch of popular headphones and ear buds. I discovered two things:
1) the impedance ranged from less than 30 ohms to over 600 ohms - that's a wide range, and it is nearly impossible to design an output stage that doesn't care about that.
2) the sensitivity of the headphones was all over the map - even after you address the fact that each manufacturer uses a slightly different means to specify sensitivity<G>!
I'd certainly try the splitter cable, but I would not be terribly disappointed if it did not work well