"This is probably a good place to ask this question. I did my first-ever sampling last weekend, and ended up using Audition to do the task. I recorded them 44.1KHz mono (drums), but Audition defaulted to a 32-bit float on saves so I just used that. Is that 32-bit buying anything at all, or just wasting space on me?"
For recording yes its wasting space. Keep in mind that your converters are incapable of recording anything above 24 bits. So the file that was created is 24 bits plus a lot of padding. This adds nothing useful to the recording at all.
Now for processing it a very different story. However, I am of the opinion that the file on disk doesn't need to be greater than 24 bits even after processing. I am sure I am alone in this view.