Vab
If my PC struggles with 96 KHz, I'll just be mad.
I understood so from you earlier post in this thread that you're going to try 96 kHz because you think your audio quality is crap. If I understood correctly, you'll be disappointed big time. If there is something wrong with your audio in a way you can clearly hear, the problem is not the sampling rate. 44,1 kHz is the CD quality, so if your gear and skills are up to the task you'll get good professional recordings with that.
Recording audio the small advantages of 96 kHz can be utilized with top-end mics, top-end treated studios and top-end monitors. If you don't have those, it's a waste of HDD/SSD space and CPU resources.
With soft synths (all plugins don't support it) it can be a little different.
Also, many cheaper sound cards, which are advertised to support 96 kHz can only record it with limited features, say, like only one mono track or similar.