WRT 32bit DimPro, if you installed the 32bit DimPro before the 64bit version, it will use the 32bit sample library. They are the same. It is pretty easy to tell if you are running a 32bit plug-in in 64bit SONAR, the plug-in name in the browser and menu will be appended with
(32-bit) and the plug-in GUI will not have the normal VST header.
The safest way to move sample libraries is NOT through the registry but using the DOS mklink command. Using either the /d or /j switch can create a link allowing relocation of any directory to another drive.