There's no button. You route the output or create a send from the channel you want to use for the side chain signal, and as destination you pick the sidechain input of your plug. This didn't really change in X3 in the sense that the Sonitus Gate/Comp has had this since the beginning. X3 added VST3 support though which makes sidechaining available for any VST3 plug that supports it. E.g. In my Waves bundle Renaissance Compressor and Renaissance Channel. The way to do it is still the same.