Enjoy. Live takes a little time to get used to but I'm sure you'll really enjoy it in the end.
Some useful beginner tips:
1. The TAB key switches between arrangement view/mode and session/clip mode. You'll want to use session/clip mode mostly, but it can be useful if you need to edit clips or loops to use arrangement mode. You can freely drag audio between the two by grabbing it and then pressing TAB.
2. Control+J bounces whatever you have selected to a clip.
3. Ccntrol+4 switches quantize on and off.
4. If you want to make sure a certain song or session always plays at a certain speed, simply add "xxxbpm" to the session launch box on the far right. Example: "Chorus A 120bpm"
5. To assign any parameter to a key or midi signal, press Control+K (for keyboard) or Control+M ( for midi), simply select the parameter with the mouse and press your key or move your midi controller. They're now linked.
6. Live, as a stability safeguard, does not automatically add midi controllers as you plug them in, nor will it recognize any that you plugged in while it was running. Plug in everything, then start up. The first time youmuse a new controller, you'll have to go into the preferences and set up whether you want to use it to send/receive clock, record and play notes/track or control the live interface (or any combination).
7. Get a dedicated controller if you are serious about using it live! ;) It really makes a huge difference when you can touch live like an instrument and feel the immediacy.