Thanks for all the helpful replies folks.
I've never heard of taskbar toolbars, I'll take a look.
I've got all PDF documents (manuals and help files) that I'm aware of in a folder which I shortcut to on the desktop. There are doubtless some/others I've missed though.
I actually quite like the old Windows compiled help format (.chm) files. I think there's a DLL you can install to allow Win 7 to read them, but it's a shame that they've fallen out of favour.