I found this course to be very helpful:
Production Mixing Mastering with Waves - 5th Edition
You can get it on Amazon - Get the one with the CD and DVDs. It has projects of different genres with all of the appropriate mastering effects applied. You can turn them off and on to hear what they do. It's relatively straight forward to go from the Waves plugins (14 day trail versions included) to your own when you have learned what to do with them. At one time, it was a Berklee course. I don't know if it still is, but is has some magic between the covers :-)